CS199285B2 - Photochromic boron-free aluminosiliceous glass - Google Patents
Photochromic boron-free aluminosiliceous glass Download PDFInfo
- Publication number
- CS199285B2 CS199285B2 CS77624A CS62477A CS199285B2 CS 199285 B2 CS199285 B2 CS 199285B2 CS 77624 A CS77624 A CS 77624A CS 62477 A CS62477 A CS 62477A CS 199285 B2 CS199285 B2 CS 199285B2
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- weight
- glass
- photochromic
- oxide
- bao
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract description 77
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims abstract description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 29
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052709 silver Inorganic materials 0.000 claims abstract description 12
- 239000004332 silver Substances 0.000 claims abstract description 12
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- -1 silver halide Chemical class 0.000 claims abstract description 6
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims abstract description 5
- 239000013078 crystal Substances 0.000 claims abstract description 5
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 22
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 20
- 239000000292 calcium oxide Substances 0.000 claims description 20
- 239000000460 chlorine Substances 0.000 claims description 20
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 15
- 229910052794 bromium Inorganic materials 0.000 claims description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 2
- 229940112669 cuprous oxide Drugs 0.000 claims description 2
- 229910000464 lead oxide Inorganic materials 0.000 claims description 2
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims 1
- 229910001923 silver oxide Inorganic materials 0.000 claims 1
- 229910052681 coesite Inorganic materials 0.000 abstract description 15
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 15
- 229910052682 stishovite Inorganic materials 0.000 abstract description 15
- 229910052905 tridymite Inorganic materials 0.000 abstract description 15
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 abstract description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 8
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 7
- 229910052593 corundum Inorganic materials 0.000 abstract description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 4
- 238000007792 addition Methods 0.000 abstract description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 17
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 16
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 15
- 230000003287 optical effect Effects 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 9
- 230000005855 radiation Effects 0.000 description 9
- 238000001816 cooling Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000005286 illumination Methods 0.000 description 5
- 239000011734 sodium Substances 0.000 description 4
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 3
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- 101100348017 Drosophila melanogaster Nazo gene Proteins 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000007496 glass forming Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- HJTAZXHBEBIQQX-UHFFFAOYSA-N 1,5-bis(chloromethyl)naphthalene Chemical compound C1=CC=C2C(CCl)=CC=CC2=C1CCl HJTAZXHBEBIQQX-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 101100350185 Caenorhabditis elegans odd-1 gene Proteins 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000048 melt cooling Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/04—Compositions for glass with special properties for photosensitive glass
- C03C4/06—Compositions for glass with special properties for photosensitive glass for phototropic or photochromic glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3813/76A GB1540471A (en) | 1976-01-30 | 1976-01-30 | Photochromic glasses |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS199285B2 true CS199285B2 (en) | 1980-07-31 |
Family
ID=9765391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS77624A CS199285B2 (en) | 1976-01-30 | 1977-01-31 | Photochromic boron-free aluminosiliceous glass |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4088501A (en]) |
| JP (1) | JPS52107016A (en]) |
| AR (1) | AR211949A1 (en]) |
| BR (1) | BR7700545A (en]) |
| CA (1) | CA1087436A (en]) |
| CS (1) | CS199285B2 (en]) |
| DD (1) | DD128805A5 (en]) |
| DE (1) | DE2703860A1 (en]) |
| FR (1) | FR2339579A1 (en]) |
| GB (1) | GB1540471A (en]) |
| IT (1) | IT1117103B (en]) |
| NL (1) | NL7700770A (en]) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR8006255A (pt) * | 1979-10-12 | 1981-04-14 | Pilkington Brothers Ltd | Vidro fotocromico de aluminio-fosfato |
| DE3204625C2 (de) * | 1982-02-10 | 1986-07-10 | Schott Glaswerke, 6500 Mainz | Alumosilico-Phosphat-Brillenglas mit einer Abbezahl über 46, mit einem Brechungsindex über 1,56 und einer sehr niedrigen Dichte |
| US4549894A (en) * | 1984-06-06 | 1985-10-29 | Corning Glass Works | Ultraviolet absorbing photochromic glass of low silver content |
| JPH0451968U (en]) * | 1990-09-11 | 1992-05-01 | ||
| US5589285A (en) * | 1993-09-09 | 1996-12-31 | Technology Management, Inc. | Electrochemical apparatus and process |
| US5445903A (en) * | 1993-09-09 | 1995-08-29 | Technology Management, Inc. | Electrochemical apparatus |
| JP3883527B2 (ja) | 2003-07-17 | 2007-02-21 | ニプロ株式会社 | トランスファーニードル |
| WO2013074779A1 (en) | 2011-11-16 | 2013-05-23 | Corning Incorporated | Ion exchangeable glass with high crack initiation threshold |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3615761A (en) * | 1968-01-31 | 1971-10-26 | Ppg Industries Inc | Phototropic articles containing thallous halide |
| GB1367903A (en) | 1971-07-12 | 1974-09-25 | Pilkington Brothers Ltd | Photochromic glasses |
| AR204329A1 (es) * | 1974-02-01 | 1975-12-22 | Jenaer Glaswerk Schott & Gen | Vidrio fototropo libre de fluor y acido borico |
-
1976
- 1976-01-30 GB GB3813/76A patent/GB1540471A/en not_active Expired
-
1977
- 1977-01-25 CA CA270,454A patent/CA1087436A/en not_active Expired
- 1977-01-26 NL NL7700770A patent/NL7700770A/xx not_active Application Discontinuation
- 1977-01-28 BR BR7700545A patent/BR7700545A/pt unknown
- 1977-01-28 FR FR7702369A patent/FR2339579A1/fr active Granted
- 1977-01-28 DD DD7700197140A patent/DD128805A5/xx unknown
- 1977-01-28 IT IT67196/77A patent/IT1117103B/it active
- 1977-01-31 US US05/764,314 patent/US4088501A/en not_active Expired - Lifetime
- 1977-01-31 CS CS77624A patent/CS199285B2/cs unknown
- 1977-01-31 DE DE19772703860 patent/DE2703860A1/de not_active Withdrawn
- 1977-01-31 JP JP884777A patent/JPS52107016A/ja active Granted
- 1977-12-31 AR AR266375A patent/AR211949A1/es active
Also Published As
| Publication number | Publication date |
|---|---|
| JPS52107016A (en) | 1977-09-08 |
| GB1540471A (en) | 1979-02-14 |
| FR2339579B1 (en]) | 1982-05-14 |
| BR7700545A (pt) | 1977-10-04 |
| DD128805A5 (de) | 1977-12-14 |
| IT1117103B (it) | 1986-02-10 |
| CA1087436A (en) | 1980-10-14 |
| JPS569464B2 (en]) | 1981-03-02 |
| US4088501A (en) | 1978-05-09 |
| DE2703860A1 (de) | 1977-08-25 |
| FR2339579A1 (fr) | 1977-08-26 |
| NL7700770A (nl) | 1977-08-02 |
| AR211949A1 (es) | 1978-04-14 |
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